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Newlight's KTA features

Large nonlinear optical coefficients

Wide angular bandwidth and small walk-off angle 

Broad temperature and spectral bandwidth 

Large electro-optic coefficients

Lower absorption in the 3-4 μm range than KTP.

Nonhydroscopic, chemically and mechanically stable 

High thermal conductivity 

High damage threshold

KTA is a positive biaxial crystal, with the principal axes X, Y, and Z ( nz>ny>nx ) parallel to the crystallographic axes a, b, and c, respectively. 

Structural and Physical Properties

Crystal Structure  

Orthorhombic, space group Pna21, point group mm2

Cell Parameters  

a=13.125Å, b=6.5716Å, c=10.786 Å, Z=8

Melting Point  

1130oC

Curie Point  

880oC

Mohs Hardness  

 ~ 5

Density  

3.45 g/cm3

Color  

colorless

Hygroscopic Susceptibility

No

Specific Heat  

0.687 J/g/K

Thermal Conductivity  

1.8 W/m/K

Electrical Conductivity  

0.7-3.4 x10-6 s/cm (c-axis, @22 oC, 1KHz)

Linear Optical Properties:

Transmitting Range    

350 nm - 5000 nm      

Refractive Indices:
               1064nm
               532nm
 

    nx             ny            nz
 1.7818      1.7866      1.8680
 1.8264      1.8331      1.9310

Sellmeier Equations
(
λ in μm)  

nx2=1.90713+1.23522λ2 /(λ2-0.19692)-0.01025λ2
ny2=2.15912+1.00099λ2 /(λ2-0.21844)-0.01096λ2
nz2=2.14768+1.29559λ2/(λ2-0.22719)-0.01436λ2

Thermo-optic Coefficients  

dnx/dT=1.1x10-5/oC, dny/dT=1.3x10-5/oC
dnz/dT=1.6x10
-5/oC   

Absorption Coefficient   

α < 1% cm-1 @1064nm and 532nm   

Nonlinear Optical Properties:

Phasematchable SHG Range

542 - 1800nm  

Nonlinear Optical Coefficients

d31=2.8pm/v, d32=4.2pm/v,
d
33=16.2pm/v,d24=3.2pm/v,
d
15=2.3pm/v

Effective Nonlinearity Expressions 

deff(II)= (d24-d15)sin2φsin2θ-(d15sin2φ+d24cos2φ)sinθ

Electro-optic Coefficients
( Low frequency )

 γ13= 11.5pm/V, γ23=15.4pm/V, γ33=37.5pm/V

Dielectric Constant

εeff=42  


NCPM Tuning Curve for 1064nm pumped OPO/OPA

With its excellent transmission at the MIR and the possibility to achieve NCPM when pumped with the common Nd lasers at ~ 1 μm, KTA is the crystal of choice for the effective generation of 3-5um through OPO/OPA.  The NCPM OPO/A can be temperature tuned by placing an x-cut crystal in an oven. The tuning curve is as follows,


 

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