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Ti:Sapphire ( Titanium-doped Sapphire, Ti:Al2O3)

Ti:Sapphire crystal is the most widely used tunable solid-state laser material combining the supreme physical and optical properties with the extremely broad lasing range.  Its lasing bandwidth can support pulses < 10fs making it the crystal of choice for femtosecond mode-locked oscillators and amplifiers.  The absorption band of Ti:Sapphire centers at ~ 490 nm so it may be conveniently pumped by various laser sources such as argon ion lasers or frequency doubled Nd:YAG, Nd:YLF, Nd:YVO4 lasers at ~ 530nm.

We can provide  large ( up to  φ120 x 80mm) Ti:Sapphire crystals.  The ends of Ti:Sapphire crystals can be coated with broadband AR @ 800nm or cut at the Brewster angle to eliminate the reflection loss.

Please contact Newlight for crystal sizes and doping levels for your applications.

Basic Properties

Chemical formula

Ti3+:Al2O3

Crystal structure

Hexagonal a=4.758, c=12.991

Density

3.98 g/cm3

Melting point

2040oC

Mohs hardness

9

Thermal conductivity

52 W/m/K

Laser action

4-level vibronic

Fluorescence lifetime

3.2 µs (T=300K)

Tuning range

660 - 1050 nm

Absorption range

400 - 600 nm

Emission peak

795 nm

Absorption peak

488 nm

Refractive index

1.76 @ 800 nm


Absorption Coefficient vs. Ti Doping Level



Standard Products

Part No. Doping  Dimensions Coating  In stock
TIS3100-D020-AR800 0.20% Dia.3.0x10mm AR@800nm Email/Call
TIS3100-D020-B 0.20% Dia.3.0x10mm Brewster ends Email/Call
TIS3100S-D020-B 0.20% 3.0x3.0x10mm Brewster ends Email/Call
TIS4100-D020-AR800 0.20% Dia.4.0x10mm AR@800nm Email/Call
TIS4100-D020-B 0.20% Dia.4.0x10mm Brewster ends Email/Call
TIS4100S-D020-B 0.20% 4.0x4.0x10mm Brewster ends Email/Call
TIS3150-D020-AR800 0.20% Dia.3.0x15mm AR@800nm Email/Call
TIS3150-D020-B 0.20% Dia.3.0x15mm Brewster ends Email/Call
TIS3150S-D020-B 0.20% 3.0x3.0x15mm Brewster ends Email/Call
TIS4150-D020-AR800 0.20% Dia.4.0x15mm AR@800nm Email/Call
TIS4150-D020-B 0.20% Dia.4.0x15mm Brewster ends Email/Call
TIS4150S-D020-B 0.20% 4.0x4.0x15mm Brewster ends Email/Call
TIS3250-D010-B 0.10% Dia.3.0x25mm Brewster ends Email/Call

Ti:Sapphire crystals are highly customized. Please contact us  for the crystals  with specified dimensions and doping concentration that best suit your applications.

Specifications on Finished Products

Orientation:   

a-cut with the rod axis normal to the optical axis c-axis.
c-cut available upon request.

Ti2O3 concentration:   

0.06 - 0.25 wt %   

Figure of Merit(FOM):  

> 250 or 150 depending on the doping level    

End configurations:   

Flat/Flat or Brewster/Brewster ends

Flatness:   

λ/10 @ 633 nm

Parallelism:   

20 arc sec

Surface finishing:   

10/5 scratch/dig to MIL-O-13830A   

Wavefront distortion:   

λ/4 per inch



 

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